Chlorine oxide

Oxides ma ọ bụ oxides nke iche iche na-akpọ compound na oxygen. Fọrọ nke nta niile ọcha na-etolite dị otú ahụ ogige. Chloro, nakwa dị ka ndị ọzọ halogens, ji dị otú ahụ ogige mma ọxịdashọn ala. All chlorine oxides bụ oké ejighị n'aka bekee, nke bụ ihe e ji mara maka oxides nke halogens. Anọ mara umi onye ụmụ irighiri nwere chlorine na oxygen.

1. Gaseous compound si edo edo ka dika uhie na agba ya na a mara isi (isi reminiscent Cl2 gas) - chlorine oxide (m). Chemical usoro Cl2O. The agbaze uche nke mwepu 116 ° C, esi okpomọkụ + 2 Celsius C. N'okpuru nkịtị ọnọdụ, ya njupụta bụ hà 3,22 kg / m³.
2. Yellow ma ọ bụ epe-odo gas na a mara isi - chlorine oxide (IV). Chemical usoro ClO2. The agbaze mgbe mwepu 59 ° C, esi ebe plus 11 Celsius C.
3. The red-aja aja na mmiri mmiri - chlorine oxide (VI). Chemical usoro Cl2O6. Agbaze ebe plus 3,5 Celsius C, esi ebe plus 203 Celsius C.
4. Colorless mmanu mmanu mmiri mmiri - chlorine oxide (VII). Chemical usoro Cl2O7. Agbaze mgbe mwepu 91,5 ° C, esi ebe plus 80 Celsius C.

Oxide chlorine ọxịdashọn ala +1 anhydride adịghị ike monobasic hypochlorous acid (HClO). Kwadebere usoro nke ya Peluso mercuric oxide site mmeghachi omume na chlorine gas dị ka otu n'ime mmeghachi omume arụmarụ: 2Cl2 + 2HgO → Cl2O + Hg2OCl2 ma ọ bụ 2Cl2 + HgO → Cl2O + HgCl2. igba ọnọdụ nke ndị a dị iche iche Jeremaya mere. Chlorine oxide (m) na-condensed na a okpomọkụ nke mwepu 60 Celsius C n'ihi na elu okpomọkụ ya erekasịchaala explosively, na itinye ụdị bụ ihe mgbawa. Cl2O okenye ihe ngwọta nke enwetara site chlorination na mmiri ma ọ bụ alkali carbonates, alkaline ụwa ọla. Oxide dissolves ọma na mmiri, nke na-hypochlorous acid a kpụrụ: Cl2O + H2O ↔ 2HClO. Ọzọkwa, ọ na-etisasịwo carbon tetrachloride.

Oxide chlorine ọxịdashọn ala +4 ma mara dioxide. Nke a ihe onwunwe e etisasịwo ke mmiri, na igirigi ibu sulphuric na acetic asịd, acetonitrile, carbon tetrachloride, na ndị ọzọ organic solvents na-amụba polarity nke enwekwu ya solubility. Na laabu na ọ na-akwado ya site na omume potassium chlorate na oxalic acid: 2KClO3 + H2C2O4 → K2CO3 + 2ClO2 + CO2 + H2O. Ebe ọ bụ na chlorine oxide (IV) bụ otu ihe mgbawa umi, ọ na-apụghị ga-echekwara na ngwọta. N'ihi nke a, silica na-eji, na onye elu na adsorbed ụdị ClO2 nwere ike ịchekwa ruo ogologo oge, mgbe na-enweghị ike tufuo contaminating ya chlorine adịghị, ebe ọ bụ na ọ na-adịghị etinye obi gị dum site na silica jel. Na ulo oru ọnọdụ ClO2 kwadebere site Mbelata na sọlfọ dioxide na ọnụnọ nke na igirigi ibu sulphuric acid, sodium chlorate: 2NaClO3 + SO2 + H2SO4 → 2NaHSO4 + 2ClO2. Ọ na-eji dị ka a bleach, e.g., akwụkwọ ma ọ bụ cellulose, wdg, nakwa dị ka sterilizing na disinfecting dị iche iche ihe.

Oxide chlorine ọxịdashọn ala +6, ọ erekasịchaala dị ka mmeghachi omume akụkụ n'elu agbaze: Cl2O6 → 2ClO3. Njikere chlorine oxide (VI) oxidizing Ozone dioxide: 2O3 + 2ClO2 → 2O2 + Cl2O6. Nke a oxide bụ ike nke na-emeghachi omume n'ụzọ na alkaline ngwọta na mmiri. Ke idaha a disproportionation mmeghachi omume ime. Ka ihe atụ, site na mmeghachi omume na potassium hydroxide: 2KOH + Cl2O6 → KClO3 + KClO4 + H2O, n'ihi nwetara chlorate na potassium perchlorate.

Higher oxide chlorine-akpọ dihlorogeptaoksid chlorine ma ọ bụ anhydride bụ a siri ike oxidant. Ọ bụ ike nke na a pin ma ọ bụ ịgbawa mgbe ewe iwe. Otú ọ dị, nke a umi bụ ọzọ mụ karịa oxides na ọxịdashọn ala +1 na +4. Disintegration ya chlorine na oxygen na-accelerated site n'iru nke ala oxides na ọnọdụ okpomọkụ adahade si 60 70 Celsius C. Chlorine oxide (VII) ike nke na-eji nwayọọ nwayọọ soluble mmiri oyi, na n'ihi mmeghachi omume na-amị chloric acid: H2O + → Cl2O7 2HClO4. Dihlorogeptaoksid kwadebere site jiri nwayọọ kpo oku perchloric acid na phosphoric anhydride: P4O10 + 2HClO4 → Cl2O7 + H2P4O11. Cl2O7 nwekwara ike ga-enwetara site na iji oleum kama site pentoxide.

Nkebi inorganic onwu, nke na-amụ halogen oxides, gụnyere oxides, chlorine, wee malite ịkpa ngwa ngwa na-adịbeghị anya, ebe ọ bụ na ndị a ogige nwere ike kpụ ọkụ n'ọnụ. Ha na-enwe ike combustors ugboelu nyefe ume instantaneously na chemical ugbu a na isi mmalite ọsọ nke ya anaghị achọ nwere ike na-achịkwa. Ihe ọzọ mere ndị mmasị - bụ ekwe omume nke synthesizing ọhụrụ dị iche iche nke inorganic ogige, e.g., chlorine oxide (VII) bụ progenitor nke perchlorates.